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What are the most widely-used, but rarely cited papers in experimental chemistry? My votes for organic synthesis would be:

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The Infrared and Ultraviolet Absorption Spectra of Cytosine and Isocytosine in the Solid State

First description of using KBr pellets for measuring the IR spectra of solids. (At least in English, a German group published something similar almost simultaneously.)

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@Steve - perfect example of what I'm looking for. – Rich Apodaca Mar 13 at 18:59

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